Verbal consent is insufficient
When a creature's spell comes into effect and affects a victim so that the victim is entitled to a saving throw against the spell, that's when the victim decides either to make that saving throw normally or to opt out of making the saving throw (effectively failing that saving throw).
Normally, what the victim said, wrote, signed, or thought prior to that decision is immaterial. On Magic on Saving Throws says, "A creature can voluntarily forgo a saving throw and willingly accept a spell’s result," but that doesn't mean that a victim can forgo a saving throw in advance.
Really, there's not an enormous gap between the meme and the reality in Pathfinder, but it is more complicated and dice are involved. In sum, the meme:
DM: The NPC says, "Loathsome finger-wiggler, make me a sword!"
PLAYER: I cast polymorph any object on the NPC and transform him into a sword. Now, DM, I know you're going to argue with me about this, but the NPC shouldn't get saving throw because this is what he wanted and…
In Pathfinder, mechanically, it goes like this:
DM: The NPC says, "Loathsome finger-wiggler, make me a sword!"
PLAYER: I cast polymorph any object on the NPC.
DM: The NPC makes a Spellcraft check to identify the spell as it's being cast. [Rolls dice.] Although you're still within his threated area, the NPC chooses not to make against you an attack of opportunity. The spell comes into effect. [Rolls dice.] You sense that your spell has failed.
In that second scenario, it's possible that the NPC failed the Spellcraft skill check. Nonetheless, when the spell comes into effect, the NPC was told to make a saving throw. Thus, rather than risk being a victim of an unknown effect—even if that effect were to bring forth for him a sword—, the NPC makes the saving throw and succeeded on it.
It's also possible that the NPC succeeded on the Spellcraft skill check and determined that the spell being cast was polymorph any object, and that's cool because that could totally bring forth a sword. However, when the NPC himself must make a saving throw, he knows that he is, in fact, the target of the spell and not the rock or whatever that the caster implied would become a sword, so the NPC makes the saving throw and succeeded on it.
The caster can totally talk up the idea that the NPC will have to forgo the saving throw to get the magic sword, and maybe that will persuade the NPC to forgo that saving throw when the time comes, but the NPC can't, like, preforgo the saving throw before he can make it!
That makes the scenario in question plausible, but also risky:
DM: The vain vampire duchess agrees to see you.
PLAYER: "Your grace, I am a mighty wizard and purveyor of appearance-improvement magic. Allow me to cast a spell that will render you even more irresistible. However, the spell requires that you lower your magical defenses against it."
DM: Make a Bluff check.
PLAYER: But I'm not Bluffing! As a housecat, she really will be even more irresistible!
DM: [Sighing.] Whatever. "Get on with it, turd," says the duchess.
PLAYER: I cast polymorph any object to transform the duchess into a kitten.
DM: The NPC makes a Spellcraft check to identify the spell as it's being cast. [Rolls dice.] She narrows her eyes at you menacingly, but she doesn't make the attack of opportunity against you. The spell comes into effect. [Rolls dice.] The duchess is transformed into a kitten. You do not sense that your spell has failed.
In that scenario, the caster doesn't know if the duchess identified the spell as it was being cast and made yet failed the saving throw, didn't identify the spell and made yet failed the saving throw, identified the spell and forwent the saving throw, or didn't identify the spell and forwent the saving throw. All the caster really knows is that the spell didn't fail.
Fortunately, this cuts both ways. PCs are no more bound to their words than NPCs. A PC who verbally agrees beforehand to accept a caster's spell doesn't actually have to when the time comes. Even if the PC swears up and down on his mother's empty grave that he'll forgo the saving throw, when it's actually time to decide whether to make the save or forgo it, that decision is still his to make.