For the following Longtable MWE, how can I make the third vertical line and the second horizontal line thicker than the other lines?
\documentclass[12pt, twoside]{article}
\usepackage{longtable}
\begin{document}
\begin{longtable}[c]{|l|c|c|c|}
\hline
& Col 2 & Col 3 & Col 4 \\ \hline
\endfirsthead
Row 2 & a & b & c \\ \hline
Row 3 & x & y & z \\ \hline
\end{longtable}
\end{document}



tabularray. It provides very intuitive interface to create complex tables where lines, spaces, alignments, etc. are easy to tune. You don't really need any other package but code may take a bit longer to compile. – Celdor Jun 06 '22 at 12:33