The peer site that AEM is trying to visit has a self signed certificate. The question is how to import the self signed certificate into the AEM truststore.
Adobe has an article about this at https://helpx.adobe.com/experience-manager/6-3/forms/using/admin-help/certificates.html
In administration console, click Settings >Trust Store Management > Certificates.
However, I cannot find "Settings" in the admin console in AEM 6.3.
Does anyone have a clue?