Consider a random variable $V$ with variance $\sigma_V^2$.
Since the covariance between a random variance and a constant is zero, I think, if $\sigma_V^2=0$, the covariance between $V$ and another random variable, say $U$, should be zero.
That is, $\sigma_V^2=0 \implies \sigma_{VU}=0$ for any random variable $U$.
I am strongly sure. But, I want to check this one more again.