$
\newcommand{\pperp}{\perp\kern-5pt\perp}
\newcommand{\npperp}{\not\perp\kern-8pt\perp}
$
First, please note that there are different definitions of a path out there and in the definition of $Z$-$\sigma$-open paths, they use the following definition for a path (unfortunately, they don't give this definition in the paper, at least I didn't find it):
A path as a sequence of consecutive edges in the graph, without any
restrictions on the types or orientations of the edges involved.
In particular, this means that a path can also go through the same node or edge multiple times.
Your first question:
You cannot find a path from $v_1$ to $v_6$ that does not contain a collider: A path starting with $v_1\to v_2\to v_5$ contains $v_2$ as a collider, so we have to go via $v_1\to v_2\to v_3\to v_4$. But however we continue this path to $v_6$, there will always be a collider in this path. Thus, all paths from $v_1$ to $v_6$ contain colliders, thus $v_1 \pperp v_6$.
Your second question:
Using the notation $Z=\{v_3, v_5\}$, we need to find a path from $v_1$ to $v_6$ that is $Z$-$\sigma$-open. Once we have that, we have shown that $v_1\npperp v_6 | Z$.
Now, the path $p = v_1\to v_2\to v_3\to v_4\to v_5\leftarrow v_4\leftrightarrow v_6$ is a $Z$-$\sigma$-open path, because:
- $p$ is $Z$-$\sigma$-open at $v_1$ because $v_1\not\in Z$ (point 1. in
the definition),
- $p$ is $Z$-$\sigma$-open at $v_2$ because of (c) in the definition,
- $p$ is $Z$-$\sigma$-open at $v_3$ because of (c) in the definition (this is different from d-separation!),
- $p$ is $Z$-$\sigma$-open at $v_4$ because of (c) in the definition,
- $p$ is $Z$-$\sigma$-open at $v_5$ because of (a) in the definition,
- $p$ is $Z$-$\sigma$-open at $v_4$ because of (b) in the definition, and
- $p$ is $Z$-$\sigma$-open at $v_6$ because $v_6\not\in Z$ (point 1. in
the definition).
In a nutshell:
We have a $\sigma$-open path through the conditioned node $v_3$ because at $v_3$ the path "stays inside a loop" and the path is open at the conditioned node $v_5$ simply because it is a collider.