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From the (excellent) Schaum's Outlines for Probability and Statistics an example from the Estimation Theory chapter shows us that the typical estimation of the variance does provide an unbiased and efficient estimation of the true variance. Yet the sqroot of that value is not so for the true standard deviation. Then .. why?

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Inspired by the comment from @NickCox I found this note on Wikipedia. We have that the n-1 term does correct for the variance but the non-linear aspect of the square root allows for only partial correction on the standard deviation. There is not a general way to get an unbiased estimate of the latter. https://en.wikipedia.org/wiki/Unbiased_estimation_of_standard_deviation

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