From an i.i.d. sample of Rayleigh r.v.'s we obtain the MLE/Method of Moments estimator
$$\hat \sigma^2_{MLE} = \frac{1}{2N}\sum_{i=1}^n x_i^2 \implies 2\hat \sigma^2_{MLE} = \frac{1}{n}\sum_{i=1}^n x_i^2$$
We see that the right hand side is the sample mean of the squared Rayleighs... and we can easily deduce by the change-of-variables formula that if $X$ follows a Rayleigh distribution with parameter $\sigma$, then the random variable $Z = X^2$ follows an Exponential distribution with scale parameter $\gamma = 2\sigma^2$.
A confidence interval for the mean of an Exponential distribution depends on the sum of the i.i.d exponentials, and the sum of i.i.d. $\sum^n Exp(\gamma) \sim Gamma(n, \gamma)$ (shape-scale paramaterization).
$$\frac{2n\bar Z}{\chi^2_{1-\frac{\alpha}{2},2n}} < \gamma < \frac{2n\bar Z}{\chi^2_{\frac{\alpha}{2},2n}} \implies \frac{2}{\chi^2_{1-\frac{\alpha}{2},2n}}\cdot Gamma(n,\gamma) < \gamma < \frac{2}{\chi^2_{\frac{\alpha}{2},2n}}\cdot Gamma(n,\gamma)$$
Since $\gamma /2 = \sigma^2$ we obtain
$$\left(\chi^2_{1-\frac{\alpha}{2},2n}\right)^{-1}\cdot Gamma(n,2\sigma^2) < \sigma^2 < \left(\chi^2_{\frac{\alpha}{2},2n}\right)^{-1}\cdot Gamma(n,2\sigma^2)$$
We have no closed form for the median $m$ of a Gamma distribution, but the Gamma becomes almost symmetric rather quickly, as the shape parameter increases in value (here equal to the sample size $n$). So the median will be almost equal to its mean, say $\mu$, which here is equal to
$$m_l \approx \mu_l = \frac{2n\sigma^2}{\chi^2_{1-\frac{\alpha}{2},2n}},\;\;\;m_u \approx \mu_u = \frac{2n\sigma^2}{\chi^2_{\frac{\alpha}{2},2n}}$$
for the lower and upper bound of the confidence interval respectively.
Now, as $n$ increases one can verify that both quantiles of the chi-squared distribution approach the degrees of freedom, here $2n$ (this happens because the chi-squared distribution becomes very concentrated around its mean value as the degrees of freedom increase),
$$n \uparrow \implies m_l, m_u \approx \sigma^2$$
So, using $\hat \sigma^2$ as the parameter instead of the unknown true value, we see why the median of this distribution is close to the MLE.
The approximate formula for the median of a $Gamma (k,\theta)$ distribution is
$$m \approx k\theta\cdot \frac{3k -0.8}{3k+0.2}$$
which in our case becomes
$$m_l \approx \mu_l\frac{3n -0.8}{3n+0.2},\;\;\; m_u \approx \mu_u\frac{3n -0.8}{3n+0.2}$$