The concatenation operator + is a binary infix operator which, when applied to lists, returns a new list containing all the elements of each of its two operands. The list.append() method is a mutator on list which appends its single object argument (in your specific example the list c) to the subject list. In your example this results in c appending a reference to itself (hence the infinite recursion).
An alternative to '+' concatenation
The list.extend() method is also a mutator method which concatenates its sequence argument with the subject list. Specifically, it appends each of the elements of sequence in iteration order.
An aside
Being an operator, + returns the result of the expression as a new value. Being a non-chaining mutator method, list.extend() modifies the subject list in-place and returns nothing.
Arrays
I've added this due to the potential confusion which the Abel's answer above may cause by mixing the discussion of lists, sequences and arrays.
Arrays were added to Python after sequences and lists, as a more efficient way of storing arrays of integral data types. Do not confuse arrays with lists. They are not the same.
From the array docs:
Arrays are sequence types and behave very much like lists, except that the type of objects stored in them is constrained. The type is specified at object creation time by using a type code, which is a single character.