Is it possible to set a picture instead of the existing characters?
This is certainly possible ─ setting the baskground image to your icon and setting the original marker's colour to transparent will produce this effect.
Example:
details summary::-webkit-details-marker {
background: url(/images/toggle-expand.png) center no-repeat;
color: transparent;
}
details[open] summary::-webkit-details-marker {
background: url(/images/toggle-collapse.png) center no-repeat;
color: transparent;
}
This only works in Webkit browsers and Chrome. You might want to consider rotating the icon instead of replacing it with a different one, in which case you can use the following:
summary::--webkit-details-marker {
transform: rotate(-90deg);
}
details[open] summary::--webkit-details-marker {
transform: rotate(0deg);
}
[dir="rtl"] summary::--webkit-details-marker {
transform: rotate(90deg);
}
[dir="rtl"] details[open] summary::--webkit-details-marker {
transform: rotate(0deg);
}
This solution rotates the icon if it is originally pointing downwards. It also factors in details elements that are within RTL parents; though be careful with this approach if mutliple text directions are used throughout the document.