Answer is
UEI
Because
TOEVAQCNXFLEFJRCUYAYQBZAOGAZATVFYHXEYVR???GUNNST
rot13 and split into trigrams is:
GBR IND PAK SYR SWE PHL NLD OMN BTN MNG ISL UKR LIE ??? THA AFG
Which are all NATO country code trigrams:
United Kingdom, India, Pakistan, Syria, Sweden, Philippines, Netherlands, Oman, Bhutan, Mongolia, Iceland, Ukraine, Liechtenstein, ?, Thailand, Afghanistan
Their capitals are:
London, New Delhi, Islamabad, Damascus, Stockholm, Manila, Amsterdam, Muscat, Thimphu, Ulaanbaatar, Reykjavik, Kiev, Vaduz, ?, Bangkok, Kabul
The countries are linked by the next one's capital starting with the last letter of the previous one's capital (including "coming back home"), so the capital of the missing entry must start with "Z" and end in "b", well there is only one such capital...
Zagreb, Croatia
...and Croatia has the NATO trigram:
HRV
rot13 to get back to the text we were presented with (thanks hexomino!):
UEI