In the comments on the MathSE question "Is Seifert-Weber space homogeneous for a Lie group?", it is claimed that if $ M $ is a manifold which admits a finite volume hyperbolic metric (constant negative sectional curvature) then there can exist no Lie group $ G $ acting (smoothly) transitively on $ M $. Why is that?
Thoughts on the case of compact surfaces: A compact hyperbolic surface must have negative Euler characteristic. Mostow, G. D., A structure theorem for homogeneous spaces, Geom. Dedicata 114, 87-102 (2005). ZBL1086.57024 proves that a compact manifold admitting a transitive action by a Lie group must have nonnegative Euler characteristic $ \chi \geq 0 $. Thus compact hyperbolic surfaces are never homogeneous.
The same Mostow paper above is used by Moishe Kohan to prove this result for 3 manifolds here https://mathoverflow.net/a/409329/387190
Update: More generally, a Lie group cannot act transitively on any complete finite volume negatively curved manifold
Apply this to $M$ hyperbolic to conclude $M = \Bbb H^n$ which is not finite volume. Kobayashi's proof echoes the argument of the comment two above mine.
– mme Sep 12 '23 at 00:06