To elaborate on Leibniz's comment that "The axioms are not, as you say, indemonstrable" (see the answer https://hsm.stackexchange.com/a/369/604): Leibniz was rather successful in choosing the appropriate axioms and/or heuristic principles for the infinitesimal calculus he developed. I would note four particularly important items.
(1) Law of Continuity. There are several formulations of this (as distinct from the Principle of Continuity). One of them is the following: The laws of the finite succeed in the infinite, and vice versa." This is described by Abraham Robinson as closely related to the Transfer Principle of infinitesimal analysis (for example, a relation such as $\sin^2 x+\cos^2 x=1$, being true for all standard inputs, would necessarily be true by the Transfer Principle for all inputs, including for example infinitesimal ones).
(2) Relation of infinite proximity. Leibniz emphasized on numerous occasions that in the calculus he worked, not with the relation of exact equality, but rather with the relation of equality up to negligible terms. This is closely related to the Standard Part principle of modern infinitesimal analysis.
(3) The dichotomy of assignable vs inassignable number. While there is clearly no construction of this anywhere in Leibniz, he postulates the existence of such a distinction, which enables him to work both with infinitesimals and (their inverses) infinite numbers.
(4) Leibniz made it clear in a pair of texts from 1695 that his infinitesimals violate the principle of comparability found in Euclid's Elements, volume 5, Definition 4 (Leibniz referred to Definition 5 following contemporary editions of Euclid). This is closely parallel to the violation of the Archimedean property in modern number systems containing infinitesimals.
Thus all in all this leads us to suggest that Leibniz was rather successful in creating the germs of an axiomatisation of infinitesimal analysis -- something that has been clearly realized only recently.