I am not sure if it is intuitive but this is because because CRS function is homogenous of degree 1.
Full derivation:
First, general formula for any arbitrary elasticity of substitution between $L$ and $K$* is given by (see Sydsæter et al. EMEA pp 430):
$$\sigma_{L,K} = \frac{-F_K'F_L'(xF_K'+ yF_L')}{xy \left( (F_L')^2F_{KK}^{''} - 2 F_K'F_L'F_{KL}'' + (F_K')^2F_{LL}''\right)}, \text{ for: } F(K,L)=c \tag{1}$$
Where c is arbitrary constant. This is our starting point.
Now by definition property of CRS production function is that they are homogenous of degree 1 (since by definition we have CRS when $F(tK,tL)= tF(K,L)$).
If $F$ is homogenous of degree 1, then the numerator of (1) will be $= −F_K'F_L'F$.
This is because of the Euler's theorem which tells us that if:
$$f(x,y) \text{ is homogenous of degree k} \implies xf_x'(x,y) + yf_y'(x,y)= kf(x,y)$$
Next Euler theorem also implies that (assuming $f$ is twice continuously differentiable) that:
$$xf_{xx}''(x,y) + yf_{yx}''(x,y)= (k-1)f_x'(x,y)$$
$$xf_{yx}''(x,y) + yf_{yy}''(x,y)= (k-1)f_y'(x,y)$$
The above implies that in our case:
$$K F_{KK}'' = - LF_{KL}'' $$ and that $$L F_{LL}'' = - K F_{LK}'' = - K F_{KL}'' $$. Hence the denominator will be given by:
$$ -F{KL}''\left( L^2 (F_L')^2 + 2KLF_K'F_L'+ K^2(F_K')^2\right)= - F_{KL}''(KF_K'+ L F_L')^2 = - F_{KL}''F^2$$
We use Euler theorem above again.
Now finally we are done:
$$\sigma_{LK} = \frac{−F_K'F_L'F}{- F_{KL}''F^2} =\frac{F_K'F_L'}{ F_{KL}''F} $$
I personally do not think the result above is very intuitive (if it is so its intuition eludes me), but it is a consequence of CRS function being homogenous of degree 1 and this result actually applies for any elasticity of substitution between two variables of arbitrary function that is homogenous of degree 1 and twice continuously differentiable.
* or $y$ and $x$ for that matter this generalizes to any elasticity of substitution problem