In response to another question, Extensions of beta theory of lambda calculus, Evgenij offered the answer:
beta + the rule {s = t | s and t are closed unsolvable terms}
where a term M is solvable if we can find a sequence of terms such that M's application to them is equal to I.
Evgenij's answer gives an equational theory over the lambda calculus, but not one characterised by a reduction system, i.e., a confluent, recursive set of rewrite rules.
Let's call an invisible equivalence over a theory of the lambda calculus, a reduction system that equates some nontrivial set of closed unsolvable lambda terms, but doesn't add any new equations involving solvable terms.
Are there any invisible equivalences over the beta theory of the lambda calculus?
Postscript An example that characterises an invisible equivalence, but is not confluent. Let M=(λx.x x) and N=(λx.x x x), two unsolvable terms. Adding the rule rewriting N N to M M induces an invisible equivalence containing M M = N N, but has the bad critical pair where N N reduces to both M M and M M N, each of which has one rewrite available, which rewrites to itself.