It's easier to take the questions out of order.
what can be said about the distribution of exponents a+b mod p when b is taken at random from Zp, but a is fixed?
If $b$ is a uniform independent random value from the range $[0, p-1]$, that is, the probability of each possible value is $1/p$, and $b$ is distributed independently from $a$, then $a+b \bmod p$ is a uniform independent (of $a$) random value from the range $[0, p-1]$; that is, the probability of $a+b \bmod p$ being any possible value from the range is also $1/p$, and information about the distribution of $a$ (such as having it be a fixed value) does not change this.
The easiest way to see this (for a fixed $a$) is to note that, for any target value $c = a+b \bmod p$, there is a unique value of $b = c-a \bmod p$ that must be selected for the value $a+b \bmod p$ to be that value. The probability of $b = c-a \bmod p$ occurring is $1/p$ (because that value is in the range, and we assumed the probability of all values in that range be $1/p$), hence the probability that $c = a+b \bmod p$ is also $1/p$.
With this, your first question is easy:
I would like to ask here why in question 2 old post, we cannot distinguish the two distributions, even with unlimited computational power?
Alice sees either $g^b$ or $g^{a+b}$; an adversary with unlimited computational power can solve the discrete log, however that gives him either $b$ or $a+b$ (for random $b$); both probability distributations are identical, and so he cannot distinguish them.