I selected the first material to be white. I understand this is the base material. Then I selected 4 faces as per the screenshot
Then I created a new colour yellow and tried to assign this to the faces but it coloured the whole thing in yellow. next screenshot
I have read some of the posts about this but cant find a solution. Is there a bug in the system?
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You have to add a new material slot and assign the faces to that slot. What you've done is simply change the material for the base colour slot.

Psyonic
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