Diamonds are carbon. Plants take in CO2 and use the carbon. Chemically, could the right kind of plant have diamonds for berries, or is there some other limiting factor?
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In what context are they possible? In reality, no. Diamonds are geology. Plants are biology. – DA. Apr 28 '15 at 04:40
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1@DA. Diamonds are crystals. Some plants can grow other crystals. http://www.asknature.org/strategy/6eb4107cbcdde41d35818191b29f60f5#.VT8Py85h3eQ – Sam Washburn Apr 28 '15 at 04:43
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5"Crystal" is a term that can mean different things. It doesn't specifically mean geology based. A diamond is very much geology based, though (immense pressure and heat). If you're OK with synthetic diamonds, and stretching how plant life works, I suppose you could come up with some sort of vapor-condensing process ala: http://en.wikipedia.org/wiki/Synthetic_diamond#Chemical_vapor_deposition – DA. Apr 28 '15 at 04:51
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@DA. I'm interested in the diamond carbon crystal structure on a large enough scale that they look like berries. – Sam Washburn Apr 28 '15 at 05:00
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Well, I go back to my initial question about context. Is this a hard science fiction story? Pure fantasy? Magic? – DA. Apr 28 '15 at 05:04
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@DA. Hard science fiction, on earth. This would be a genetically engineered plant probably. – Sam Washburn Apr 28 '15 at 05:07
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1Well, if that's the case, the natural diamond wouldn't work. I think you'd have to leverage playing off of the chemical process for cultured diamonds. – DA. Apr 28 '15 at 05:16
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Cultured diamonds sounds like the way to put it. – Sam Washburn Apr 28 '15 at 05:32
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8It is more likely to have a plant bearing a carbon nanotube melon than a diamond berry. – user6760 Apr 28 '15 at 06:28
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Re berry size: see my main answer. Have diamond forems grow out on their old dead skeletons like coral. – JDługosz Apr 28 '15 at 13:48
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@user6760 ...I'm not eating that. – James Apr 28 '15 at 13:58
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3Real cool question. Even better would be to get answers with energy requirements, duration of diamond growth, details of the synthesis process... :-) not asking for much! – Sheraff Apr 28 '15 at 16:24
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Sounds like a brand new type of alchemy to me – geotheory Apr 29 '15 at 13:48
8 Answers
A plant could produce a diamond chemically by laying down carbon atoms in the right crystalline formation. Heat and pressure are for geological diamonds, they aren't relevant when you're dealing with atoms at a time. There is no reason for them to do this, evolution-wise, but since you're talking about genetic engineering that doesn't matter. Forming diamonds this way would only be limited by how much carbon the plant can get. They could strip hydrogen, oxygen, etc. from any organic compound, but it would probably be much more efficient to feed it carbon directly as either graphite or charcoal.
The problem is not with "diamond" but with "berry". From Wikipedia:
...a berry is a fleshy fruit produced from a single flower and containing one ovary.
Which a diamond definitely is not. But in terms of diamond trees with clusters of jewels, it's possible.
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33"laying down carbon atoms" is easier to say than to do. Any time you have a surface of pure carbon, you have to prevent oxygen and hydrogen from attaching to the said surface, and their attachment may be more favorable energetically. I'm not sure whether a pure biological process may serve as a perfect filter: there certainly isn't one now, but it's hard to say whether this is possible in principle. – IMil Apr 28 '15 at 08:05
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3Or just allow hydrogen/oxygen to bond to the surface, and remove it on the fly when you need to. Or perhaps the outermost layer could be a graphene sheet,which wouldn't bond with H/O, and would be 'crumpled' into a new layer of diamond as the next graphene layer is formed? – evankh Apr 28 '15 at 09:09
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7@Sam: Most of the "berries" you eat are probably not berries botanically speaking but drupes, pomes and other things. But yes, you are eating the reproductive organs of other life forms. But then, people happily eat rocky mountain oysters. – RedGrittyBrick Apr 28 '15 at 10:49
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2Sure there's an evolutionary reason if they can attach their seeds to the diamonds. People want sparkly things and will take them all over the place, and then the seeds end up all over the place. It's the same evolutionary principle that made fruit delicious. – R.. GitHub STOP HELPING ICE Apr 28 '15 at 14:37
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2Imagine the evolutionary advantage of being the one plant most protected by the human race on the entire planet. At least until the economy crashes and they all get burned, making the remaining organic diamonds untradable by law. – Apr 28 '15 at 18:37
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@SeanBoddy By comparison with the ebony tree, now endangered in much of its natural range, I don't anticipate good things for the diamondberry bush. – Resonating Apr 28 '15 at 18:40
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@Resonating, the ebony tree wouldn't be in as much trouble if you didn't have to kill it to get what you wanted. But, yes, poaching would be more troublesome than in the case of exotic lumber, unless it's very easy to pluck the "berries" rather than slash the plant. But can you imagine the security measures? Jeez. This world would be weird. – Apr 28 '15 at 18:46
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It would be extremely expensive to plant a bush and take a long time to bear fruit. I anticipate well-defended greenhouses and well-paid gardeners. – Resonating Apr 28 '15 at 18:53
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3If diamonds grew from plants they would be worth way less, as much of it's value comes from it being a scarce and hard to obtain resource. As an example, before humans knew how to make glass, it was considered a jewel in ancient times because the only source came from meteorites that fell in the desert. See worthless yellow rocks – quarkex Apr 29 '15 at 00:39
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4Plants get 100% of their carbon from air (or very close to it, say 99.999%) and since 50% of wood is carbon (45% oxygen, 4% hydrogen) it means that wood is mainly created from air. Plants are very efficient at converting air into solid mass and much, much less efficient at sucking solid mass from the ground or water so feeding them graphite or charcoal directly would be inefficient. Indeed, plants essentially created charcoal from air (we just roast the wood to create charcoal). – slebetman Apr 29 '15 at 02:31
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1Does anyone know the energy input needed to drive this reaction? Is it something within the range of what a plant could accomplish? – Loren Pechtel Apr 30 '15 at 04:02
Quite possibly! Biology has the advantage of being able to micromanage what is going on chemically and mechanically. This often allows life to achieve results that humans currently achieve with huge chambers at incredible temperatures and pressures. With advances in genetic engineering we will become able to leverage this more and more.
We can now make synthetic diamonds quite easily using Chemical vapour deposition. Although it would be quite difficult for a plant to "handle" gaseous carbon due to its extreme temperature, the plant could instead liberate single carbon atoms at high energy. Of course this would be happening simultaneously all over the surface of the diamond, and the diamond would slowly grow, probably over years.
Note that the diamond itself would not be "alive"—it would certainly not have any reproductive capacity. Perhaps living cells could be embedded within it, though. It's possible that the enzymes and/or cells that surround the diamond during its formation would occasionally get trapped within it, particularly with "early prototypes" of the plant. I expect this would manifest as cloudiness of the diamonds. Conceivably such diamonds could become fashionable due to the knowledge that it is caused by living matter trapped inside, at which point genetic engineers might intentionally manipulate the process to create visible patterns within the diamonds.
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2Sounds similar to how oysters make pearls. The diamonds could just be an allergic reaction to a foreign irritant. – slebetman Apr 29 '15 at 02:35
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1We make synthetic golden-brown, polycrystalline diamonds quite easily using CVD. Clear-ish single-crystal diamonds are much more difficult. – Jasper Sep 29 '18 at 07:22
Diamonds are considerably more than just carbon. According to this, there are believed to be four steps to the formation of diamonds:
- Bury carbon dioxide 100 miles into Earth.
- Heat to about 2,200 degrees Fahrenheit.
- Squeeze under pressure of 725,000 pounds per square inch.
- Quickly rush towards Earth’s surface to cool.
I'm fairly certain that plants combust a few degrees below 2,200 degrees Fahrenheit.
There are a few methods we've managed to produce synthetic diamonds with, but both involve high temperatures.
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1I was thinking more along the lines of the plant molecularly assembling diamonds. But I'm not knowledgable about chemical processes enough to know if that's even feasible. – Sam Washburn Apr 28 '15 at 04:28
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2@SamWashburn Creating a diamond isn't a chemical process; it's a physical one. – Frostfyre Apr 28 '15 at 05:00
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3Perhaps the "easiest" path would be pressure and heat, but is it (at least theoretically) possible, for instance, to assemble carbon into diamond on a nano scale using proteins or other biological processes? Or is there some kind of energy barrier or other limiting factor to overcome? – Sam Washburn Apr 28 '15 at 05:11
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22This is a description of the geological formation of diamonds. Assuming plants would need to go through that process to produce diamonds is like assuming animals couldn't produce carbon dioxide without being on fire. – user2357112 Apr 28 '15 at 07:08
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@user2357112 it's all semantics at this point, but if we're talking natural diamonds (which would be likely what a plant would make) then we are talking about the geological formation of them. – DA. Apr 28 '15 at 07:33
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@user2357112 The OP used the reality-check tag. I provided the process by which diamonds are formed on Earth. Could there be some biological entity somewhere in the universe that can produce diamonds? Sure, it's possible. But it doesn't exist on Earth. – Frostfyre Apr 28 '15 at 12:31
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@Frostfyre: If the OP has a world with plants that produce diamonds then it certainly wouldn't be our Earth. If you say:
Could there be some biological entity somewhere in the universe that can produce diamonds? Sure- then that answers the question. – slebetman Apr 29 '15 at 02:34 -
@slebetman Note the reality-check tag. I don't know the biological processes of extraterrestrial organisms. Had the OP not included that tag, I wouldn't have pointed out how diamonds are formed. – Frostfyre Apr 29 '15 at 03:34
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2Reality-check does not mean Earth check. Typically it is used to check if something is possible in our universe without breaking rules of physics. – slebetman Apr 29 '15 at 04:18
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@Frostfyre The tag may be reality check, but the site is Word Building. The earth is already built, so questions are obviously not asking about the earth. – Shane Apr 30 '15 at 16:38
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@Shane There's been so many up- and downvotes on this answer so far that I can't do anything but laugh. Apparently, the WB community can't decide if this is a good answer or not. – Frostfyre Apr 30 '15 at 16:41
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@Frostfyre I imagine the upvotes are from people who don't know that there are other ways to make diamonds. I would have upvoted this answer because I didn't know better, either. – Shane Apr 30 '15 at 17:54
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It is likely that the natural process for making diamonds includes dissolving carbon in a metal, crystallizing out the carbon, and physically breaking up the products until the metal traces are removed. The dissolving with metal stage greatly reduces the pressures required. – Jasper Sep 29 '18 at 07:25
Definitely not naturally - for the simple reason this is completely impractical from evolutionary point of view.
Diamond requires a lot of energy to form. Even if the process was atom-by-atom, with the biology handily providing easily detached placeholders preventing the surface from oxidation (forming weak bonds with the diamond's carbon, then breaking them and replacing with more carbon atoms making the diamond grow) attaching each new atom would take a lot of energy; energy the plant must obtain on top of maintaining its own growth and life processes. Energy better spent on more useful endeavors like growing taller to outgrow competing plants, or producing more seeds to increase chance of finding fertile soil for them.
OTOH artificial species like this would be possible. I doubt it would resemble berry bushes as it would need a massive leaf system to acquire all the needed solar energy and carbon dioxide, a massive root system to provide water and nutrients to the massive leaf system, a "skeleton" to support both, and the diamonds would not be exposed to the air, instead growing inside some fruits that would prevent oxidation and contamination of the growth surface.
So - replace your diamond berries with diamond trees :)
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5@SamWashburn: Ask at Chemistry.SE for heat produced by burning a unit weight (say, 1 gram) of diamond. That's the pure energy in Joules. Triple that for all the extraneous processes needed for the construction process (usual estimate for biological processes). Divide by time taken for the diamond growth for "wattage input" and compare to other plants (adding standard plant self-maintenance margin, e.g. if producing diamond takes X, generic plant survival takes Y, your plant takes X+Y (+ some, as Y increases survival costs)). – SF. Apr 28 '15 at 09:10
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@SF. this is probably a candidate for "best answer-for-another-SE-site-in-a-comment" :) – msouth Apr 29 '15 at 14:39
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@SF. Looks like -6.527kJ from burning a 1 ct. diamond. So that's about 19.5kJ using your times 3 estimate. I'd like to solve for time actually... Any idea where i can find the "wattage input" of other plants? http://chemistry.stackexchange.com/a/29585/15880 – Sam Washburn Apr 30 '15 at 05:33
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1Photosynthesis efficiency "3 to 6% of total solar radiation." Peak equatorial zenith sunlight is 1120 W/m^2 but you should rather look at 24h averages in moderate climate; sustainability.SE can give you these as they are related to solar power. "Usable" leaf surface of given plant will be somewhat more (30%?) than area (graphical projection, from direction of the Sun) occupied by the plant. (the extra is from reflections, sky luminescence and light filtering through top leaves). – SF. Apr 30 '15 at 05:57
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1@SF. Back of the napkin estimate. Say 50% peak equatorial wattage, 1m^2 for the leaf area (including the 30% extra), 8 hours of exposure daily, and 3% efficiency. That's 483kJ? If 75% of that is used to maintain the plant, that's still 6 diamonds a day. Is that right? I'm unsure about is the leaf area of a berry bush. – Sam Washburn Apr 30 '15 at 07:34
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2@SamWashburn: 1) -50% night time; 2: (integral[0-pi] sin(x)) / pi = 2/pi = 63% - proportion of daylight morning-evening vs peak all the time; 3) 50% for moderate climate area. Probably even less as the light must get through thicker layer of atmosphere, and that's not accounting for cloudy and partially overcast days. I'd say 5% of the peak is closer to the ballpark figure. 100 MJ/day * 5%(exposure) * 5%(efficiency) = 250kJ At ~75% - 60kJ towards building the diamonds; 20kJ per diamond, so closer to 3 carats per day. Of course not three 1-ct per day, rather 400 0.25-ct diamonds per month. – SF. Apr 30 '15 at 08:44
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1Re: "Diamond requires a lot of energy to form" – that's actually the opposite of the truth. Bond formation releases energy (it is exothermic). To make diamond from (say) methane, you have to put energy in to break the existing C-H bonds, but you get energy out by forming C-C (and H-H) bonds; the overall reaction would be slightly exothermic. The problem here is NOT that diamond is hard to make, it's that graphite is EASIER to make (more exothermic) at normal temperature / pressure. So, unless you supervise each individual atom, pure carbon will form as graphite rather than diamond. – bobtato Oct 13 '18 at 23:41
In A Deepness in the Sky, Vinge referred casually to strata bearing diamond forems. You might also think about diatoms which produce a cell wall of silica, literally glass.
I think it's plausible that microorganisms could produce structures of crystalline diamond or carbon fiber, in a variety of manners that real life produces inorganic shells in or around itself. Vinge used forems rather than more familiar diatoms, I think because the test (shell) is like a seashell, extruded around the cell. But diatoms produce glass in their cell walls, so you might imagine a mechanism where it is created in a completely enclosed chamber and then the outer skin is disposable leaving the protective shell to face the harsh environment.
Others have pointed out that nanotechnology or "life" could plausibility deposit crystals atom by atom, but I think carbon fiber is more realistic: look how carbon fiber is actually manufactured: start with an organic molecule that has a very common carbon hexagon backbone, and then removing all the extra atoms leaving only the carbon hexagons.
But I'd like to note that these structures won't be solid rock diamond crystals, but sparse filigree and thin walls, like diatom shells.
What might be the use of something like diatomaceous earth that's composed of diamond rather than silica? Obviously abrasives, but could a useful composite material be made?
If such a thing existed in nature, technological society would figure out how the nanotechnology works inside the cell, and apply the ideas to synthetic processes; or use selective breeding to produce algae that grow long fibers.
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Since plants can use carbo for diamond-berrys. I'd like to use Iron for steel punch (I think steel legs would be too heavy to carry) – CoffeDeveloper Apr 28 '15 at 17:54
Contrary to some of the answers here, there is no chemical reason why a plant couldn't manufacture diamonds (source: bachelor's degree in chemistry). The individual alkane bonds that make up diamond are nothing special, and living cells make and break that sort of bond all the time.
Artificial synthesis techniques work on atoms in bulk, whereas biological systems can synthesize molecules more or less atom-by-atom, and for this reason the constraints that make diamond hard to synthesize by bulk methods are mostly irrelevant to biochemistry.
As a very loose analogy, imagine you had a sack of Lego bricks and you wanted to join them all together into a solid block. In bulk chemistry terms this means continually shaking ("heating") and compressing the sack, and the bricks would join together to some extent, because the joined state is more space-efficient ("thermodynamically stable"), but it would take longer than the lifetime of the universe to get to a single solid block, unless you were shaking the bag really, really fast. As a living cell, you'd simply open the sack and put the bricks together one by one.
Biochemistry isn't magic, and there are thermodynamic costs to working in this organized way. In the above analogy, the living cell first needs to manufacture complicated specialist enzymes to grip and combine Lego bricks, and that background work will require a great deal of energy overall. The difference is, though, the energy isn't expended all at once, so it doesn't necessarily imply high temperatures or pressures.
In terms of evolutionary biology, there would need to be a good reason for the plant to evolve this feature (evolution doesn't waste energy). Even then, you could debate whether it's feasible at all in terms of energy landscapes; see e.g. the discussion about evolution and wheels.
If it were a genetically engineered feature, the question is not whether it could be done but only how hard it would be. Possibly the answer is "insanely hard", but that's the kind of question you can't answer until someone does it.
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As a follow-up to knave's answer, for a diamond-fruit, I'm picturing a walnut-like fruit which has a fleshy outer layer, a hard middle layer, and the living part of the seed in the center.
The outer layer would prevent Hydrogen and Oxygen from binding to the Carbon while more layers of Carbon are deposited. A cut in the outer layer could potentially disrupt the carbon-laying process while the fruit is growing.
The diamond layer, like a walnut shell, would need a seam; a weak line along which the shell will split when the living inner part sprouts from the seed. The seam must be much weaker than diamond, as no seedling is going to have the ability to punch through even a thin layer of diamond. The shell might grow with several seams or just one, depending on the plant. It will also need a path for nutrients to enter the inside of the shell, which could be the seam or a hole. Depending on how the shell splits, you may end up with bowl-shaped diamonds...not ideal.
The inner part would need enough food for it to grow until the seedling applies enough force to split the shell along its seam. As such, it would probably be close to the size of a walnut, or even as large as a coconut.
One potential problem is that while diamond is hard, it is not flexible. Most plant matter is flexible because plants are always changing their shape. A diamond fruit would need to grow to its full size before it started growing a diamond layer.
One last thing. Diamonds are "valuable" because of market manipulation. There are much prettier stones and much rarer stones out there. Their scarcity in the jewel market is manufactured scarcity. Industrial diamonds are valuable because of their hardness, but they are common and can be manufactured already. The cost to develop a plant that grows diamonds would far outweigh the value gained from producing diamonds with plants, for both jewelry and industrial uses. It's more likely that an eccentric billionaire would fund development than that a diamond company would.
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If cells can build diamonds layer by layer, there's no reason why cells could not also dissolve the diamond again, it just needs some different enzymes. So the seedling could dissolve the diamond shell when it is ready to emerge. – JanKanis Oct 03 '18 at 15:13
While it wouldn't be a berry I can think of a reason for a diamond to evolve: A plant with diamond needles inside it would be akin to being poisonous but it would be even harder for a creature to evolve resistance.
I doubt there is an evolutionary path that leads to this, though.
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