If the number of observations is reasonably large and the distribution of responses not too jammed up one end or the other, a plain two-sample t-test may be reasonable, especially if you would be prepared to add such an item to similar Likert-scale items to produce a scale, were additional items available (this illustrates preparedness to assume that the scale-intervals are equispaced).
It is possible to take a nonparametric approach such as with a Mann-Whitney/Wilcoxon but the heavy ties make this approach only about as good as the $t$ in many cases.
A more easily justified approach might be to deal with the ordered categorical response more directly, and look at a regression model that deal with it (where there's a dummy to signify membership of the second group), such as say proportional odds models, cumulative logit ("grouped-continuous") models, continuation-ratio models, polytomous logistic models, adjacent-category logistic models or stereotype logistic models.